Surfactants, also known as surface-active agents, are compounds that can significantly reduce the surface tension between two liquids, liquid-gas, and liquid-solid interfaces. Reducing surface tension is the most fundamental function of surfactants, and this property makes them widely used in industrial production and daily life.
Surfactant molecules have a unique amphiphilic structure, with one end being a hydrophilic group (water-loving) and the other end being a hydrophobic group (water-repelling, oil-loving). This structure allows them to align at interfaces, thereby reducing interfacial tension.
Surface tension refers to the tension acting along any boundary on a liquid’s surface, caused by the imbalance of molecular forces in the surface layer. It acts like an “elastic skin” on the liquid.
Morning dew on leaves and dripping water from a tap form spheres due to surface tension. Even water striders (insects) can stand on water because surface tension supports their weight.
Fig: Water droplets formed by surface tension
Surfactants are widely used as emulsifiers, wetting agents, solubilizers, dispersants, foaming agents, detergents, and Stain remover. The following are six core mechanisms of action:
| Type | Chemical Category | Examples | Main Application Fields |
|---|---|---|---|
| Cationic Surfactants | Quaternary Ammonium | Benzalkonium Chloride, Benzalkonium Bromide, Dodecyl Trimethyl Ammonium Chloride (1231/1631/1831) | |
| Anionic Surfactants | Sulfate Esters, Sulfonates, Phosphates, Carboxylates | AES, LAS-30, AEO-9P, AEC-9H, Fatty Acid Potassium Soap Series (LPS-30) | Detergents, Shampoos, Toothpaste, Industrial Cleaners |
| Amphoteric Surfactants | Betaines, Amino Acids, Imidazolines, Amine Oxides | CAB, CHSB, Sodium Lauroyl Sarcosinate, CAD-40, OA-12, OA-14 | Mild Detergents, Baby Products, Cosmetics, Personal Care Products |
| Nonionic Surfactants | Alkanolamides, Alkyl Polyglycosides, Alcohol Ethers, Fatty Acid Ester Ethers< | CDEA1:1.2, APG0810, AEO-9, Tween 20/40/60/80, PEG Series | Emulsifiers, Solubilizers, Wetting Agents, Food Additives |
| Others Surfactants | Specialty Additives | Fluorocarbon Surfactants, Silicone Surfactants | Oilfield Additives, Firefighting Foam, Specialty Coatings |
Note: This article provides a general classification. For specific product inquiries, please refer to detailed technical data sheets (TDS). The views expressed here are for reference only.